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Copper/diamond composites emerge as advanced packaging heat-spreader materials

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At Semicon Taiwan, Cu/diamond composites reached about 800 W/m·K thermal conductivity, versus about 400 W/m·K for pure copper, SemiAnalysis reports.

The composites can also be tuned to roughly 6–10 ppm/K CTE, closer to silicon's ~3 ppm/K than copper's ~17 ppm/K, reducing warpage.

The main obstacle is the copper–diamond interface, where carbide-forming elements such as Ti, Cr, Mo, or W are added, and excess carbide lowers conductivity.

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Copper is starting to hit its limits in advanced packaging.
Pure Cu is ~400 W/m·K, while at Semicon Taiwan there are debut of Cu/diamond composites reaching ~800 W/m·K, helping spread heat faster and reduce local hotspots. They can also reduce warpage: silicon is ~3 ppm/K CTE vs copper at ~17 ppm/K, while Cu/diamond can be tuned closer to ~6–10 ppm/K.

The challenge is the Cu/diamond interface. Copper does not naturally bond well with diamond, so Ti, Cr, Mo, or W are often added to form a carbide bonding layer. But too much carbide hurts thermal conductivity, making interface thickness critical. Compared with simply alloying Cu, the industry is working on pre-coating diamond particles using PVD or CVD giving much tighter control.

Source: SemiAnalysis · x.comPublished · added here